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可控组装微纳马达的自热泳运动

Self-thermophoretic motion of controlled assembled micro-/nanomotors.

作者信息

Lin Xiankun, Si Tieyan, Wu Zhiguang, He Qiang

机构信息

Key Laboratory of Microsystems and Microstructures Manufacturing, Ministry of Education, Micro/Nanotechnology Research Centre, Harbin Institute of Technology, Harbin 150080, China.

出版信息

Phys Chem Chem Phys. 2017 Sep 13;19(35):23606-23613. doi: 10.1039/c7cp02561k.

Abstract

As artificial active colloids, micro-/nanomotors (MNMs) can convert energy from the environment into mechanical motion in different fluids, showing potential applications in diverse fields such as targeted drug delivery and photothermal therapy. However, chemical fuels for typical catalytic MNMs, e.g., hydrogen peroxide, are highly toxic to organisms, and thus fuel-free MNMs are required. Recently, we have developed near-infrared light (NIR) propelled MNMs through integrating plasmonic gold nanoshells into nanoparticles or layer-by-layer assemblies in an asymmetric manner. In this perspective, we give an account of self-thermophoresis motion of these NIR-powered MNMs. The design of the motor architectures, as well as the theoretical study on the propulsion mechanism, is highlighted. We believe that the insights into self-thermophoretic motion would pave the way to access powerful MNMs for future applications and to explore interesting collective behaviors of active matter.

摘要

作为人工活性胶体,微纳马达(MNMs)能够将环境中的能量转化为在不同流体中的机械运动,在靶向给药和光热治疗等多个领域展现出潜在应用。然而,典型催化微纳马达的化学燃料,如过氧化氢,对生物体具有高毒性,因此需要无燃料的微纳马达。最近,我们通过以不对称方式将等离子体金纳米壳整合到纳米颗粒或逐层组装体中,开发出了近红外光(NIR)驱动的微纳马达。在此视角下,我们阐述了这些近红外驱动微纳马达的自热泳运动。重点介绍了马达结构的设计以及推进机制的理论研究。我们相信,对自热泳运动的深入理解将为未来应用开发强大的微纳马达以及探索活性物质有趣的集体行为铺平道路。

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