Feng Yuquan, Zhong Zhiguo, Wang Hongwei, Fan Huitao, Bi Dongqin, Wang Lu, Xing Zhengzheng, Qiu Dongfang
College of Chemistry and Pharmacy Engineering, Nanyang Normal University, Nanyang, 473061, P. R. China.
Chemistry. 2017 Jul 21;23(41):9962-9967. doi: 10.1002/chem.201702207. Epub 2017 Jun 30.
A novel open-framework copper borovanadate, with a 6-connected topological net and 1D 8-membered ring channels, has been obtained for the first time. The compound not only exhibits a unique -B O (OH)-Cu-B(OH) linkage and features the largest ratio between TM (Cu ) and the borovanadate anion, but also possesses enhanced catalytic performance, high recyclability, and stability during the oxidation of benzylic C-H bonds.
首次获得了一种新型的开放框架硼钒酸铜，它具有六连接拓扑网络和一维八元环通道。该化合物不仅展现出独特的 -B O (OH)-Cu-B(OH) 键，且具有过渡金属（铜）与硼钒酸根阴离子之间最大的比例，还在苄基 C-H 键的氧化过程中具有增强的催化性能、高可回收性和稳定性。
