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一种具有催化潜力的新型三维开放骨架锌硼钒酸盐在α-苯乙醇氧化中的应用。

A New 3-D Open-Framework Zinc Borovanadate with Catalytic Potentials in α-Phenethyl Alcohol Oxidation.

机构信息

State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, China.

Institute of Catalysis for Energy and Environment, College of Chemistry and Chemical Engineering, Shenyang Normal University, Shenyang 110034, China.

出版信息

Molecules. 2019 Feb 1;24(3):531. doi: 10.3390/molecules24030531.

DOI:10.3390/molecules24030531
PMID:30717129
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC6384951/
Abstract

A novel 3-D open-framework zinc borovanadate [Zn₆(en)₃][(VO)₆(VO)₆O₆(BO(OH)₆)·(H₂O)]₂·14H₂O (, en = ethylenediamine) was hydrothermally obtained and structurally characterized. The framework was built from [VBO(OH)₆(H₂O)] polyanion clusters bridged by Zn(en) complex fragments. The compound not only possessed a three-dimensional open-framework structure with unique plane-shaped channels, but also exhibited excellent catalytic activities for the oxidation of α-phenethyl alcohol.

摘要

一种新型的 3-D 开架锌硼钒酸盐[Zn6(en)3][(VO)6(VO6O6)(BO(OH)6)·(H2O)]2·14H2O(en = 乙二胺)通过水热法得到并进行了结构表征。该骨架由[VBO(OH)6(H2O)]多阴离子簇通过 Zn(en)配合物片段桥接而成。该化合物不仅具有独特的平面形通道的三维开架结构，而且对α-苯乙醇的氧化具有优异的催化活性。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/12ee/6384951/1c4b912d8cec/molecules-24-00531-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/12ee/6384951/840decfe0832/molecules-24-00531-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/12ee/6384951/6c19d9246ed2/molecules-24-00531-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/12ee/6384951/7496a4fdbcb8/molecules-24-00531-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/12ee/6384951/cf2913ba53c1/molecules-24-00531-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/12ee/6384951/7bc8e0df8901/molecules-24-00531-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/12ee/6384951/1c4b912d8cec/molecules-24-00531-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/12ee/6384951/840decfe0832/molecules-24-00531-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/12ee/6384951/6c19d9246ed2/molecules-24-00531-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/12ee/6384951/7496a4fdbcb8/molecules-24-00531-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/12ee/6384951/cf2913ba53c1/molecules-24-00531-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/12ee/6384951/7bc8e0df8901/molecules-24-00531-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/12ee/6384951/1c4b912d8cec/molecules-24-00531-g006.jpg

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本文引用的文献

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Dalton Trans. 2015 Nov 21;44(43):18731-6. doi: 10.1039/c5dt03425f.
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