College of Chemistry and Pharmacy Engineering, Nanyang Normal University, Nanyang 473061, China.
College of Chemistry and Chemical Engineering, Luoyang Normal University, Luoyang, 471022, P. R. China.
Dalton Trans. 2022 Oct 4;51(38):14413-14419. doi: 10.1039/d2dt02575b.
A novel 3D open-framework copper borovanadate with a unique crown-shaped anion [(VO)(VO)BO(OH)] and the largest ratio of Cu/borovanadate anions (6/1) has been successfully synthesized and systematically studied. The compound not only possesses high stability in a wide pH range of 3.2-10.8 (DMF solution), but also exhibits excellent catalytic activities for selective oxidation of sulfides.
一种新颖的 3D 开架型铜硼钒酸盐，具有独特的冠形阴离子[(VO)(VO)BO(OH)]和最大的 Cu/硼钒酸盐阴离子比例（6/1），已被成功合成并进行了系统研究。该化合物不仅在 3.2-10.8（DMF 溶液）的宽 pH 范围内具有高稳定性，而且对硫化物的选择性氧化表现出优异的催化活性。
