Lehrstuhl für Chemische Reaktionstechnik, Friedrich-Alexander-Universität Erlangen-Nürnberg, 91058 Erlangen, Germany; email:
Linde AG, Technology & Innovation, Group R&D, 82049 Pullach, Germany.
Annu Rev Chem Biomol Eng. 2017 Jun 7;8:445-471. doi: 10.1146/annurev-chembioeng-060816-101334.
Future energy systems will be determined by the increasing relevance of solar and wind energy. Crude oil and gas prices are expected to increase in the long run, and penalties for CO emissions will become a relevant economic factor. Solar- and wind-powered electricity will become significantly cheaper, such that hydrogen produced from electrolysis will be competitively priced against hydrogen manufactured from natural gas. However, to handle the unsteadiness of system input from fluctuating energy sources, energy storage technologies that cover the full scale of power (in megawatts) and energy storage amounts (in megawatt hours) are required. Hydrogen, in particular, is a promising secondary energy vector for storing, transporting, and distributing large and very large amounts of energy at the gigawatt-hour and terawatt-hour scales. However, we also discuss energy storage at the 120-200-kWh scale, for example, for onboard hydrogen storage in fuel cell vehicles using compressed hydrogen storage. This article focuses on the characteristics and development potential of hydrogen storage technologies in light of such a changing energy system and its related challenges. Technological factors that influence the dynamics, flexibility, and operating costs of unsteady operation are therefore highlighted in particular. Moreover, the potential for using renewable hydrogen in the mobility sector, industrial production, and the heat market is discussed, as this potential may determine to a significant extent the future economic value of hydrogen storage technology as it applies to other industries. This evaluation elucidates known and well-established options for hydrogen storage and may guide the development and direction of newer, less developed technologies.
未来的能源系统将取决于太阳能和风能的相关性日益增强。从长远来看,原油和天然气价格预计将上涨,而 CO 排放的罚款将成为一个相关的经济因素。太阳能和风力发电的成本将大幅降低,以至于通过电解生产的氢气在价格上具有竞争力,可与天然气制氢相媲美。然而,为了应对来自波动能源的系统输入的不稳定性,需要覆盖全功率(兆瓦)和全能量存储量(兆瓦时)的储能技术。特别是氢气,作为一种有前途的二次能源载体,可用于在吉瓦时至太瓦时的规模上储存、运输和分配大量和非常大量的能量。然而,我们也讨论了 120-200kWh 规模的能量存储,例如,在使用压缩氢气存储的燃料电池汽车中,用于车载氢气存储。本文重点讨论了在这种不断变化的能源系统及其相关挑战下,氢气存储技术的特点和发展潜力。因此,特别强调了影响不稳定运行的动态、灵活性和运行成本的技术因素。此外,还讨论了可再生氢气在移动性、工业生产和热能市场中的应用潜力,因为这种潜力在很大程度上可能决定了氢气存储技术在其他行业的未来经济价值。这种评估阐明了已知的和成熟的氢气存储选项,并可能为较新的、欠发达的技术的发展和方向提供指导。