Renewable Materials and Nanotechnology Group, Department of Chemical Engineering, KU Leuven, Campus Kortrijk, Etienne Sabbelaan 53, 8500 Kortrijk, Belgium.
Nanoscale. 2017 Jun 29;9(25):8525-8554. doi: 10.1039/c7nr00400a.
Cellulose and gold nanoparticles have exciting characteristics and new combinations of both materials may lead to promising functional nanocomposites with unique properties. We have reviewed current research on cellulose-gold nanoparticle composite materials, and we present an overview of the preparation methods of cellulose-gold composite materials and discuss their applications. We start with the nanocomposite fabrication methods, covering in situ gold reduction, blending, and dip-coating methods to prepare gold-cellulose nanocomposite hybrids. We then move on to a discussion of the ensuing properties where the combination of gold nanoparticles with cellulose results in functional materials with specific catalytic, antimicrobial, sensing, antioxidant and Surface Enhanced Raman Scattering (SERS) performance. Studies have also been carried out on orientationally ordered composite materials and on the chiral nematic phase behaviour of these nanocomposites. To exert even more control over the structure formation and the resultant properties of these functional materials, fundamental studies on the physico-chemical interactions of cellulose and gold are necessary to understand better the driving forces and limitations towards structuring of gold-cellulose hybrid materials.
纤维素和金纳米粒子具有令人兴奋的特性,两者的新组合可能会导致具有独特性能的有前途的功能纳米复合材料。我们回顾了纤维素-金纳米粒子复合材料的当前研究,并介绍了纤维素-金复合材料的制备方法及其应用的概述。我们从纳米复合材料的制备方法开始,涵盖了原位金还原、共混和浸涂方法来制备金-纤维素纳米复合材料杂化物。然后,我们继续讨论随之而来的性质,其中金纳米粒子与纤维素的结合导致具有特定催化、抗菌、传感、抗氧化和表面增强拉曼散射(SERS)性能的功能材料。还对取向有序复合材料以及这些纳米复合材料的手性向列相行为进行了研究。为了对这些功能材料的结构形成和所得性质进行更多的控制,需要对纤维素和金的物理化学相互作用进行基础研究,以更好地理解驱动因素和限制因素,从而构建金-纤维素杂化材料。