Sun Kai, Lv Yunhe, Shi Zuodong, Mu Shiqiang, Li Changhao, Wang Xin
College of Chemistry and Chemical Engineering, Anyang Normal University, Anyang 455000, P. R. China.
Org Biomol Chem. 2017 Jun 27;15(25):5258-5262. doi: 10.1039/c7ob01061c.
A novel and environmentally benign method for C-S and C-N bond formation by the direct amidosulfenylation of alkenes has been developed under metal-free conditions. Various alkenes and azoles were transformed into the corresponding β-azolyl sulfides in ionic liquids. The wide substrate scope, good functional group tolerance, and ease of operation make this reaction attractive for the synthesis of nitrogen- and sulfur-containing molecules.
在无金属条件下，已开发出一种通过烯烃的直接氨磺酰化形成C-S和C-N键的新颖且环境友好的方法。各种烯烃和唑类在离子液体中转化为相应的β-唑基硫化物。广泛的底物范围、良好的官能团耐受性和操作简便性使得该反应对于含氮和含硫分子的合成具有吸引力。
