Wan Wen, Li Jialiang, Ma Guobin, Chen Yunrong, Jiang Haizhen, Deng Hongmei, Hao Jian
Department of Chemistry, Innovative Drug Research Center, Shanghai University, China.
Org Biomol Chem. 2017 Jun 27;15(25):5308-5317. doi: 10.1039/c7ob00955k.
A silver-catalyzed oxidative decarboxylative gem-difluoromethylenation of difluoroacetates with activated alkenes under mild reaction conditions has been developed. This radical cascade reaction provides a new method for the construction of a variety of gem-difluoromethylenated oxindoles.
已开发出一种在温和反应条件下，银催化二氟乙酸酯与活性烯烃的氧化脱羧偕二氟亚甲基化反应。这种自由基串联反应为构建多种偕二氟亚甲基化的氧化吲哚提供了一种新方法。
