稳定的镍（II）-氨氧基自由基配合物的生成与表征
Generation and characterisation of a stable nickel(ii)-aminoxyl radical complex.
作者信息
Parrot Arnaud, Morimoto Yuma, Paria Sayantan, Sugimoto Hideki, Fujieda Nobutaka, Itoh Shinobu
机构信息
Department of Material and Life Science, Division of Advanced Science and Biotechnology, Graduate School of Engineering, Osaka University, 2-1 Yamadaoka, Suita, Osaka 565-0871, Japan.
出版信息
Dalton Trans. 2017 Jun 27;46(25):8013-8016. doi: 10.1039/c7dt01789h.
A stable nickel(ii)-aminoxyl radical complex was generated by the reaction of a nickel(ii) complex supported by a tren ligand (tris(2-aminoethyl)amine) having bulky m-terphenyl substituents (TIPT: 3,5-bis(2,6-diisopropylphenyl)phenyl) and m-CPBA (m-chloroperoxybenzoic acid). The formation mechanism of the nickel(ii)-aminoxyl radical complex was examined.
由带有庞大间三联苯取代基（TIPT：3,5-双（2,6-二异丙基苯基）苯基）的三乙撑四胺（tren）配体（三（2-氨基乙基）胺）支持的镍（II）配合物与间氯过氧苯甲酸（m-CPBA）反应生成了一种稳定的镍（II）-氨氧自由基配合物。对镍（II）-氨氧自由基配合物的形成机理进行了研究。
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