Parrot Arnaud, Morimoto Yuma, Paria Sayantan, Sugimoto Hideki, Fujieda Nobutaka, Itoh Shinobu
Department of Material and Life Science, Division of Advanced Science and Biotechnology, Graduate School of Engineering, Osaka University, 2-1 Yamadaoka, Suita, Osaka 565-0871, Japan.
Dalton Trans. 2017 Jun 27;46(25):8013-8016. doi: 10.1039/c7dt01789h.
A stable nickel(ii)-aminoxyl radical complex was generated by the reaction of a nickel(ii) complex supported by a tren ligand (tris(2-aminoethyl)amine) having bulky m-terphenyl substituents (TIPT: 3,5-bis(2,6-diisopropylphenyl)phenyl) and m-CPBA (m-chloroperoxybenzoic acid). The formation mechanism of the nickel(ii)-aminoxyl radical complex was examined.
由带有庞大间三联苯取代基（TIPT：3,5-双（2,6-二异丙基苯基）苯基）的三乙撑四胺（tren）配体（三（2-氨基乙基）胺）支持的镍（II）配合物与间氯过氧苯甲酸（m-CPBA）反应生成了一种稳定的镍（II）-氨氧自由基配合物。对镍（II）-氨氧自由基配合物的形成机理进行了研究。
