Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University, 21 Nanyang Link, Singapore, 637371, Singapore.
National Research Center of Geoanalysis, Chinese Academy of Geological Sciences, Beijing, 100037, China.
Adv Mater. 2017 Aug;29(30). doi: 10.1002/adma.201701139. Epub 2017 Jun 19.
Crystalline porous materials are important in the development of catalytic systems with high scientific and industrial impact. Zeolites, ordered mesoporous silica, and metal-organic frameworks (MOFs) are three types of porous materials that can be used as heterogeneous catalysts. This review focuses on a comparison of the catalytic activities of zeolites, mesoporous silica, and MOFs. In the first part of the review, the distinctive properties of these porous materials relevant to catalysis are discussed, and the corresponding catalytic reactions are highlighted. In the second part, the catalytic behaviors of zeolites, mesoporous silica, and MOFs in four types of general organic reactions (acid, base, oxidation, and hydrogenation) are compared. The advantages and disadvantages of each porous material for catalytic reactions are summarized. Conclusions and prospects for future development of these porous materials in this field are provided in the last section. This review aims to highlight recent research advancements in zeolites, ordered mesoporous silica, and MOFs for heterogeneous catalysis, and inspire further studies in this rapidly developing field.
结晶多孔材料在具有高科学和工业影响力的催化体系的发展中非常重要。沸石、有序介孔硅和金属有机骨架（MOFs）是可作为多相催化剂使用的三种多孔材料。本综述重点比较了沸石、介孔硅和 MOFs 的催化活性。在综述的第一部分，讨论了这些多孔材料与催化相关的独特性质，并突出了相应的催化反应。在第二部分，比较了沸石、介孔硅和 MOFs 在四种常见有机反应（酸、碱、氧化和加氢）中的催化行为。总结了每种多孔材料在催化反应中的优缺点。最后一部分给出了对该领域这些多孔材料未来发展的结论和展望。本综述旨在强调沸石、有序介孔硅和 MOFs 在多相催化方面的最新研究进展，并激发该快速发展领域的进一步研究。
