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单层 MoS2 的热致发光。

Thermal Light Emission from Monolayer MoS.

机构信息

Institute of Photonics, Vienna University of Technology, Gußhausstraße 27-29, 1040, Vienna, Austria.

Skolkovo Institute of Science and Technology, 3 Nobel Street, Skolkovo, Moscow Region, 143026, Russia.

出版信息

Adv Mater. 2017 Aug;29(31). doi: 10.1002/adma.201701304. Epub 2017 Jun 19.

Abstract

Layered transition metal dichalcogenide semiconductors, such as MoS and WSe , exhibit a range of fascinating properties and are being currently explored for a variety of electronic and optoelectronic devices. These properties include a low thermal conductivity and a large Seebeck coefficient, which make them promising for thermoelectric applications. Moreover, transition metal dichalcogenides undergo an indirect-to-direct bandgap transition when thinned down in thickness, leading to strong excitonic photo- and electroluminescence in monolayers. Here, it is demonstrated that a MoS monolayer sheet, freely suspended in vacuum over a distance of 150 nm, emits visible light as a result of Joule heating. Due to the poor transfer of heat to the contact electrodes, as well as the suppressed heat dissipation through the underlying substrate, the electron temperature can reach ≈1500-1600 K. The resulting narrow-band light emission from thermally populated exciton states is spatially located to an only ≈50 nm wide region in the center of the device and goes along with a negative differential electrical conductance of the channel.

摘要

层状过渡金属二卤化物半导体,如 MoS 和 WSe ,具有一系列迷人的性质,目前正在被探索用于各种电子和光电子器件。这些性质包括低导热率和大的塞贝克系数,这使得它们在热电应用中很有前景。此外,过渡金属二卤化物在厚度减薄时会经历从间接带隙到直接带隙的转变,导致单层中产生强烈的激子光致发光和电致发光。在这里,证明了在 150nm 的距离内自由悬浮在真空中的 MoS 单层薄片会因焦耳加热而发出可见光。由于热量难以传递到接触电极,以及通过底层衬底抑制散热,电子温度可达 ≈1500-1600K。热激发激子态的窄带光发射在空间上局限于器件中心仅 ≈50nm 宽的区域,并伴随着通道的负微分电导。

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