炔基铜（I）化合物的三氟甲基化和氟烷基硒化反应
Trifluoromethyl- and Fluoroalkylselenolations of Alkynyl Copper(I) Compounds.
作者信息
Ghiazza Clément, Billard Thierry, Tlili Anis
机构信息
Institute of Chemistry and Biochemistry (ICBMS-UMR CNRS 5246), Univ Lyon, Université Lyon 1, CNRS, 43 Bd du 11 Novembre 1918, 69622, Villeurbanne, France.
CERMEP-in vivo imaging, Groupement Hospitalier Est, 59 Bd Pinel, 69003, Lyon, France.
出版信息
Chemistry. 2017 Jul 26;23(42):10013-10016. doi: 10.1002/chem.201702028. Epub 2017 Jul 5.
The successful perfluoroalkylselenolation of alkynyl copper(I) compounds is described herein. The reaction occurs under oxidant free conditions at room temperature. This convenient one-pot procedure is based on the in situ generation of trifluoromethylselenyl chlorides. The developed system shows high functional group tolerance and also promotes the employment of fluoroalkyl derivatives.
本文描述了炔基铜（I）化合物成功的全氟烷基硒化反应。该反应在无氧化剂条件下于室温发生。这种便捷的一锅法基于三氟甲基硒酰氯的原位生成。所开发的体系显示出高官能团耐受性，并且还促进了氟烷基衍生物的应用。
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