Shitov Oleg P, Tartakovsky Vladimir A, Golovanov Ivan S, Sukhorukov Alexey Yu, Ioffe Sema L
N. D. Zelinsky Institute of Organic Chemistry (ZIOC), Russian Science Academy, Leninsky prospect, 47, 1119991, Moscow, Russia.
Dmitry Mendeleev University of Chemical Technology of Russia, Miusskaya sq. 9, 125047, Moscow, Russia.
Chem Asian J. 2017 Sep 5;12(17):2237-2244. doi: 10.1002/asia.201700603. Epub 2017 Aug 10.
A general approach to the synthesis of borohydride complexes containing one or two dinitroamide fragments has been suggested. Based on a smooth substitution of halide in haloborane or dibromoborane complexes with N,N-dinitroamide salts, this method provides various N,N-dinitroamidoboranes complexes in good yields and in analytically pure form. By means of spectroscopic and computational methods, it was demonstrated that dinitroamidoborane complexes could form as both B,N- and B,O-isomers, which did not interconvert at ambient temperature.
