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全无机卤化物钙钛矿纳米晶:光电材料的新研究前沿。

Fully-Inorganic Trihalide Perovskite Nanocrystals: A New Research Frontier of Optoelectronic Materials.

机构信息

School of Chemistry and Environmental Engineering, Jiangsu University of Technology, Changzhou, Jiangsu, 213001, P. R. China.

Department of Chemistry, The Hong Kong University of Science and Technology, Clear Water Bay, Kowloon, Hong Kong, P. R. China.

出版信息

Adv Mater. 2017 Aug;29(32). doi: 10.1002/adma.201700775. Epub 2017 Jun 22.

Abstract

All-inorganic trihalide perovskite nanocrystals (NCs) are emerging as a new class of superstar semiconductors with excellent optoelectronic properties and great potential for a broad range of applications in lighting, lasing, photon detection, and photovoltaics. This article provides an up-to-date review on the developments of fully-inorganic trihalide perovskite NCs by emphasizing their controllable solution fabrication strategies, structural phase transformation, tunable optoelectronic properties, stability, as well as their photovoltaic and optoelectronic applications. Among the properties to be surveyed, particular focus is on the size-, shape-, and composition-dependent photoluminescence properties. Finally, by identifying new challenges, suggestions are provided for further research and potential development of this area.

摘要

全无机三卤化物钙钛矿纳米晶体(NCs)作为一类具有优异光电性能的新兴超级半导体,在照明、激光、光子探测和光伏等广泛应用领域具有巨大的潜力。本文通过强调其可控的溶液制备策略、结构相转变、可调谐光电性能、稳定性以及在光伏和光电应用方面的研究进展,对全无机三卤化物钙钛矿 NCs 的发展进行了最新的综述。在要调查的性质中,特别关注的是尺寸、形状和组成依赖性的光致发光性质。最后,通过确定新的挑战,为该领域的进一步研究和潜在发展提供了建议。

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