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使用明胶-磷酸锆纳米复合材料从水环境中高效光催化降解有毒染料及其抗菌活性。

Efficient photocatalytic degradation of toxic dyes from aqueous environment using gelatin-Zr(IV) phosphate nanocomposite and its antimicrobial activity.

作者信息

Thakur Manita, Sharma Gaurav, Ahamad Tansir, Ghfar Ayman A, Pathania Deepak, Naushad Mu

机构信息

School of Chemistry, Shoolini University, Solan 173212, Himachal Pradesh, India.

School of Chemistry, Shoolini University, Solan 173212, Himachal Pradesh, India.

出版信息

Colloids Surf B Biointerfaces. 2017 Sep 1;157:456-463. doi: 10.1016/j.colsurfb.2017.06.018. Epub 2017 Jun 20.

Abstract

In the present study, gelatin-Zr(IV) phosphate nanocomposite (GT/ZPNC) was synthesized by sol-gel method by mixing the gelatin gel into the inorganic part Zr (IV) phosphate (ZP). The GT/ZPNC was characterized by Fourier transform infrared spectroscopy, thermogravimetric analysis, scanning electron microscopy (SEM), transmission electron micron scope (TEM), X-ray powder diffraction (XRD) and X-ray photoelectron spectroscopy (XPS). The photodegradation activity of GT/ZPNC was explored for the removal of methylene blue (MB) and fast green (FG) dyes from aqueous solution. It was found that 87.81% MB and 89.91% FG were degraded within five hours. Also, the kinetics of photocatalytic degradation for MB and FG was investigated via pseudo first-order kinetic model with higher regression coefficient values (R). The antimicrobial efficiency of GT/ZPNC was investigated against E. coli.

摘要

在本研究中,通过溶胶 - 凝胶法将明胶凝胶与无机部分磷酸锆(ZP)混合合成了明胶 - 磷酸锆纳米复合材料(GT/ZPNC)。通过傅里叶变换红外光谱、热重分析、扫描电子显微镜(SEM)、透射电子显微镜(TEM)、X射线粉末衍射(XRD)和X射线光电子能谱(XPS)对GT/ZPNC进行了表征。研究了GT/ZPNC从水溶液中去除亚甲基蓝(MB)和固绿(FG)染料的光降解活性。结果发现,在五小时内87.81%的MB和89.91%的FG被降解。此外,通过具有较高回归系数值(R)的伪一级动力学模型研究了MB和FG的光催化降解动力学。研究了GT/ZPNC对大肠杆菌的抗菌效率。

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