Institut für Makromolekulare Chemie, Albert-Ludwigs-Universität Freiburg, Stefan-Meier-Str. 31, 79104, Freiburg, Germany.
Physical Chemistry and Centre for Nanointegration Duisburg-Essen, Universität Duisburg-Essen, Schützenbahn 70, 45127, Essen, Deutschland.
Angew Chem Int Ed Engl. 2017 Sep 4;56(37):10992-10994. doi: 10.1002/anie.201703765. Epub 2017 Jul 5.
Beyond the crew cut: Highly asymmetric block copolymers self-assemble into microparticles with inverse morphologies far beyond the crew-cut regime. These particles enclose highly ordered channel systems with simple cubic, double diamond, and hexagonally packed hollow-hoop symmetry. The extensive interface and confinement of these particles could enable applications in the storage of cargo, templating, and chemical reactions.
高度不对称嵌段共聚物自组装成具有远超出平头式发型范围的逆形态的微粒。这些粒子包含具有简单立方、双菱形和六方密排空心环对称的高度有序的通道系统。这些粒子的广泛界面和限制作用可以在货物储存、模板和化学反应等方面得到应用。