Ohtsu Hiroyoshi, Kawano Masaki
Department of Chemistry, School of Science, Tokyo Institute of Technology, 2-12-1 Ookayama, Meguro-ku, Tokyo 152-8550, Japan.
Chem Commun (Camb). 2017 Aug 3;53(63):8818-8829. doi: 10.1039/c7cc04277a.
Kinetic assembly is an important method for obtaining desired materials in chemical synthesis and materials science. We highlight the kinetic assembly of porous coordination networks, which promote the production of interactive pore sites. The interactive pore sites can activate or stabilize guest molecules. The properties of interactive pores are typified by iodine chemisorption and small sulfur encapsulation. Using interactive pores, we trapped small sulfur allotropes, such as S, cyclo-S, bent-S, and S, demonstrating the importance of interactive pore sites. Here, we address the important aspects of interactive pore sites created by kinetic assembly of porous coordination networks.
动力学组装是化学合成和材料科学中获得所需材料的重要方法。我们重点介绍了多孔配位网络的动力学组装，它促进了交互式孔隙位点的产生。交互式孔隙位点可以激活或稳定客体分子。交互式孔隙的性质以碘化学吸附和小硫封装为典型特征。利用交互式孔隙，我们捕获了小的硫同素异形体，如S、环-S、弯曲-S和S，证明了交互式孔隙位点的重要性。在此，我们阐述了由多孔配位网络的动力学组装产生的交互式孔隙位点的重要方面。
