Pd(II)/联吡啶催化的芳基硼酸与α,β-不饱和羧酸的共轭加成反应。β-季碳取代羧酸的合成。
Pd(II)/Bipyridine-Catalyzed Conjugate Addition of Arylboronic Acids to α,β-Unsaturated Carboxylic Acids. Synthesis of β-Quaternary Carbons Substituted Carboxylic Acids.
机构信息
State and Local Joint Engineering Laboratory for Novel Functional Polymeric Materials, Jiangsu Key Laboratory of Advanced Functional Polymer Design and Application, Key Laboratory of Organic Synthesis of Jiangsu Province, Green Polymer and Catalysis Technology Laboratory (GAPCT), College of Chemistry, Chemical Engineering and Materials Science, Soochow University , 199 Ren'ai Road, Suzhou 215123, P. R. China.
出版信息
J Org Chem. 2017 Aug 4;82(15):8023-8030. doi: 10.1021/acs.joc.7b01248. Epub 2017 Jul 24.
Pd(II)/bipyridine-catalyzed conjugate addition of arylboronic acids to α,β-unsaturated carboxylic acids (including β,β-disubstituted acrylic acids) was developed and optimized, which provided a mild and convenient method for the highly challenging synthesis of β-quaternary carbons substituted carboxylic acids.
Pd(II)/联吡啶催化的芳基硼酸与α,β-不饱和羧酸（包括β,β-二取代丙烯酸）的共轭加成被开发和优化，为高挑战性的β-季碳取代羧酸的合成提供了一种温和、便捷的方法。
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