阳离子 Pd(II)/联吡啶催化的芳基硼酸与β,β-二取代烯酮的共轭加成：季碳原子的构建。
Cationic Pd(II)/bipyridine-catalyzed conjugate addition of arylboronic acids to beta,beta-disubstituted enones: construction of quaternary carbon centers.
机构信息
State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Road, Shanghai 200032, China.
出版信息
Org Lett. 2010 Jun 4;12(11):2536-9. doi: 10.1021/ol100767u.
PMID:20450192
Abstract
Cationic Pd(II)-catalyzed addition of arylboronic acids to beta,beta-disubstituted enones in high yields was developed. This method provided an efficient method for the construction of quaternary carbon centers, and only 0.5 mol % of Pd(II) catalyst was needed.
摘要
发展了一种高产的钯(II)催化芳基硼酸与β,β-二取代烯酮加成的方法。该方法为构建季碳原子中心提供了一种有效的方法，仅需 0.5 mol%的钯(II)催化剂。
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