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Enantioselective Synthesis of Acyclic α-Quaternary Carboxylic Acid Derivatives through Iridium-Catalyzed Allylic Alkylation.
Angew Chem Int Ed Engl. 2017 Sep 11;56(38):11545-11548. doi: 10.1002/anie.201707015. Epub 2017 Aug 9.
2
Enantioselective Synthesis of Vicinal All-Carbon Quaternary Centers via Iridium-Catalyzed Allylic Alkylation.
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3
Iridium-Catalyzed Stereoselective Allylic Alkylation Reactions with Crotyl Chloride.
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Stereodivergent Allylic Substitutions with Aryl Acetic Acid Esters by Synergistic Iridium and Lewis Base Catalysis.
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Iridium-Catalyzed Enantioselective Allylic Substitution of Aliphatic Esters with Silyl Ketene Acetals as the Ester Enolates.
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Enantio-, diastereo-, and regioselective iridium-catalyzed asymmetric allylic alkylation of acyclic β-ketoesters.
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Iridium-Catalyzed Diastereoselective and Enantioselective Allylic Substitutions with Acyclic α-Alkoxy Ketones.
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Enantioselective modular synthesis of 2,4-disubstituted cyclopentenones by iridium-catalyzed allylic alkylation.
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2
Construction of Vicinal Quaternary Centers via Ru-Catalyzed Enantiospecific Allylic Substitution with Lithium Ester Enolates.
J Am Chem Soc. 2024 Aug 28;146(34):23674-23679. doi: 10.1021/jacs.4c07690. Epub 2024 Aug 19.
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Scope and Mechanistic Probe into Asymmetric Synthesis of α-Trisubstituted-α-Tertiary Amines by Rhodium Catalysis.
J Am Chem Soc. 2023 Sep 13;145(36):19642-19654. doi: 10.1021/jacs.3c04211. Epub 2023 Aug 31.
4
Hydroxy-directed iridium-catalyzed enantioselective formal β-C(sp)-H allylic alkylation of α,β-unsaturated carbonyls.
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7
Iridium-catalyzed enantioselective olefinic C(sp)-H allylic alkylation.
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10
CuH-Catalyzed Regio- and Enantioselective Hydrocarboxylation of Allenes: Toward Carboxylic Acids with Acyclic Quaternary Centers.
J Am Chem Soc. 2021 Apr 7;143(13):4935-4941. doi: 10.1021/jacs.1c01880. Epub 2021 Mar 24.

本文引用的文献

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The Catalytic Enantioselective Construction of Molecules with Quaternary Carbon Stereocenters.
Angew Chem Int Ed Engl. 1998 Mar 2;37(4):388-401. doi: 10.1002/(SICI)1521-3773(19980302)37:4<388::AID-ANIE388>3.0.CO;2-V.
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Iridium-Catalyzed Diastereo-, Enantio-, and Regioselective Allylic Alkylation with Prochiral Enolates.
ACS Catal. 2016 Sep 2;6(9):6207-6213. doi: 10.1021/acscatal.6b01886. Epub 2016 Aug 17.
3
Enantioselective Iridium-Catalyzed Allylic Alkylation Reactions of Masked Acyl Cyanide Equivalents.
Org Lett. 2017 Apr 7;19(7):1527-1529. doi: 10.1021/acs.orglett.7b00449. Epub 2017 Mar 14.
4
Study of Intermediates in Iridium-(Phosphoramidite,Olefin)-Catalyzed Enantioselective Allylic Substitution.
J Am Chem Soc. 2017 Mar 15;139(10):3603-3606. doi: 10.1021/jacs.6b12421. Epub 2017 Mar 7.
5
Synthesis of α-Quaternary Formimides and Aldehydes through Umpolung Asymmetric Copper Catalysis with Isocyanides.
J Am Chem Soc. 2017 Feb 15;139(6):2184-2187. doi: 10.1021/jacs.6b12881. Epub 2017 Feb 1.
6
Stereodivergent Allylic Substitutions with Aryl Acetic Acid Esters by Synergistic Iridium and Lewis Base Catalysis.
J Am Chem Soc. 2017 Jan 11;139(1):87-90. doi: 10.1021/jacs.6b11692. Epub 2016 Dec 22.
7
Iridium-Catalyzed Stereoselective Allylic Alkylation Reactions with Crotyl Chloride.
Angew Chem Int Ed Engl. 2016 Dec 23;55(52):16092-16095. doi: 10.1002/anie.201609960. Epub 2016 Nov 28.
8
Enantioselective Synthesis of Quaternary Stereocenters via Chromium Catalysis.
Org Lett. 2016 Oct 7;18(19):5094-5097. doi: 10.1021/acs.orglett.6b02540. Epub 2016 Sep 13.
9
Iridium-Catalyzed Regio- and Enantioselective Allylic Substitution of Trisubstituted Allylic Electrophiles.
Angew Chem Int Ed Engl. 2016 Sep 12;55(38):11651-5. doi: 10.1002/anie.201607053. Epub 2016 Aug 17.

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