具有季碳立体中心的分子的催化对映选择性构建。
The Catalytic Enantioselective Construction of Molecules with Quaternary Carbon Stereocenters.
作者信息
Corey Elias J, Guzman-Perez Angel
机构信息
Department of Chemistry and Chemical Biology" Harvard University, 12 Oxford Street, Cambridge, MA, 02138 (USA), Fax: (+1) 617-495-0376.
出版信息
Angew Chem Int Ed Engl. 1998 Mar 2;37(4):388-401. doi: 10.1002/(SICI)1521-3773(19980302)37:4<388::AID-ANIE388>3.0.CO;2-V.
Abstract
A long-standing challenge to synthesis can now be met through the use of new and powerful catalytic asymmetric reactions for the assembly of complex chiral molecules with quaternary stereocenters from achiral building blocks. The reaction sequence shown below is just one example discussed in this review.
摘要
长期以来合成方面的一个挑战现在可以通过使用新型且强大的催化不对称反应来应对，这些反应可用于从非手性构件组装具有季碳立体中心的复杂手性分子。下面所示的反应序列只是本综述中讨论的一个例子。
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