Hydrogen activation using a novel tribenzyltin Lewis acid.

Over the last decade there has been an explosion in the reactivity and applications of frustrated Lewis pair (FLP) chemistry. Despite this, the Lewis acids (LAs) in these transformations are often boranes, with heavier -block elements receiving surprisingly little attention. The novel LA BnSnOTf () has been synthesized from simple, inexpensive starting materials and has been spectroscopically and structurally characterized. Subtle modulation of the electronics at the tin centre has led to an increase in its Lewis acidity in comparison with previously reported RSnOTf LAs, and has facilitated low temperature hydrogen activation and imine hydrogenation. Deactivation pathways of the RSn LA core have also been investigated.This article is part of the themed issue 'Frustrated Lewis pair chemistry'.