de Juan Ares Jorge, Schibille Nadine
IRAMAT-CEB, UMR 5060, CNRS, Orléans, France.
PLoS One. 2017 Jul 26;12(7):e0182129. doi: 10.1371/journal.pone.0182129. eCollection 2017.
One hundred and forty-one glass fragments from medieval Ciudad de Vascos (Toledo, Spain) were analysed by laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS). The glasses fall into three types according to the fluxing agents used: mineral natron, soda-rich plant ash, and a combination of soda ash and lead. The natron glasses can be assigned to various established primary production groups of eastern Mediterranean provenance. Different types of plant ash glasses indicate differences in the silica source as well as the plant ash component, reflecting changing supply mechanisms. While the earlier plant ash groups can be related to Islamic glasses from the Near East, both in terms of typology and composition, the chemical signature of the later samples appear to be specific to glass from the Iberian Peninsula. This has important implications for our understanding of the emerging glass industry in Spain and the distribution patterns of glass groups and raw materials. The plant ash that was used for the Vascos glasses is rich in soda with low levels of potash, similar to ash produced in the eastern Mediterranean. It could therefore be possible that Levantine plant ash was imported and used in Islamic period glass workshops in Spain. Unlike central and northern Europe where an independent glass industry based on potassium-rich wood ash developed during the Carolingian period, the prevalence of soda ash and soda ash lead glass on the Iberian Peninsula indicates its commercial and technological interconnection with the Islamic east. Our study thus traces several stages leading to the development of a specifically Spanish primary glassmaking industry.
对来自中世纪巴斯克城(西班牙托莱多)的141片玻璃碎片进行了激光烧蚀电感耦合等离子体质谱分析(LA-ICP-MS)。根据所使用的助熔剂,这些玻璃可分为三种类型:天然碳酸钠、富钠植物灰以及纯碱和铅的混合物。天然碳酸钠玻璃可归为东地中海产地的多个既定原生生产组。不同类型的植物灰玻璃表明硅源以及植物灰成分存在差异,反映出供应机制的变化。虽然早期的植物灰组在类型学和成分方面都可与近东的伊斯兰玻璃相关,但后期样品的化学特征似乎是伊比利亚半岛玻璃所特有的。这对于我们理解西班牙新兴的玻璃工业以及玻璃组和原材料的分布模式具有重要意义。用于巴斯克玻璃的植物灰富含纯碱且钾含量低,类似于东地中海地区产生的灰。因此,有可能是从黎凡特进口植物灰并在西班牙的伊斯兰时期玻璃工坊中使用。与中欧和北欧不同,在加洛林时期,基于富含钾的木灰发展起了独立的玻璃工业,伊比利亚半岛上纯碱和纯碱铅玻璃的盛行表明其与伊斯兰东部在商业和技术上的相互联系。我们的研究因此追溯了导致西班牙特定原生玻璃制造工业发展的几个阶段。