Deelen Joop van, Omar Ahmed, Barink Marco
TNO/Solliance, High Tech Campus 21, 5656 AE Eindhoven, The Netherlands.
TNO/Holst, High Tech Campus 31, 5656 AE Eindhoven, The Netherlands.
Materials (Basel). 2017 Apr 7;10(4):392. doi: 10.3390/ma10040392.
The conductivity of transparent front contacts can be improved by patterned metallic nanowires, albeit at the cost of optical loss. The associated optical penalty can be strongly reduced by texturization of the cell stack. Remarkably, the nanowires themselves are not textured and not covered in our design. This was shown by optical modeling where the width of the nanowire, the texture height and the texture period were varied in order to obtain a good insight into the general trends. The optical performance can be improved dramatically as the reflection, which is the largest optical loss, can be reduced by 95% of the original value. The spectra reveal absorption in the Cu(In,Ga)Se₂ (CIGS) layer of 95% and reflection below 2% over a large part of the spectrum. In essence, a virtually black CIGS cell stack can be achieved for textured cells with a metal nanogrid. Moreover, it turned out that the ratio between the width of the nanowire and the height of the texture is a critical parameter for optical losses.
通过图案化金属纳米线可以提高透明正面接触的导电性,尽管这是以光学损耗为代价的。通过对电池堆叠体进行纹理化处理,可以大幅降低相关的光学损耗。值得注意的是,在我们的设计中,纳米线本身没有纹理且未被覆盖。这通过光学建模得到了证明,在光学建模中,改变纳米线的宽度、纹理高度和纹理周期,以便深入了解一般趋势。由于反射是最大的光学损耗,其可降低至原始值的95%,因此光学性能可得到显著改善。光谱显示,在很大一部分光谱范围内,Cu(In,Ga)Se₂(CIGS)层的吸收率为95%,反射率低于2%。从本质上讲,对于具有金属纳米网格的纹理化电池,可以实现几乎黑色的CIGS电池堆叠体。此外,结果表明,纳米线宽度与纹理高度之比是光学损耗的关键参数。