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柔性聚（3,4-乙撑二氧噻吩）：聚苯乙烯磺酸盐/聚吡咯/纸纳米复合薄膜的热电性能

Thermoelectric Properties of Flexible PEDOT:PSS/Polypyrrole/Paper Nanocomposite Films.

作者信息

Li Jun, Du Yong, Jia Runping, Xu Jiayue, Shen Shirley Z

机构信息

School of Materials Science and Engineering, Shanghai Institute of Technology, 100 Haiquan Road, Shanghai 201418, China.

CSIRO Manufacturing, Clayton South, VIC 3169, Australia.

出版信息

Materials (Basel). 2017 Jul 11;10(7):780. doi: 10.3390/ma10070780.

DOI:10.3390/ma10070780
PMID:28773141
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC5551823/
Abstract

Flexible poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate)/polypyrrole/paper (PEDOT:PSS/PPy/paper) thermoelectric (TE) nanocomposite films were prepared by a two-step method: first, PPy/paper nanocomposite films were prepared by an in situ chemical polymerization process, and second, PEDOT:PSS/PPy/paper TE composite films were fabricated by coating the as-prepared PPy/paper nanocomposite films using a dimethyl sulfoxide-doped PEDOT:PSS solution. Both the electrical conductivity and the Seebeck coefficient of the PEDOT:PSS/PPy/paper TE nanocomposite films were greatly enhanced from 0.06 S/cm to 0.365 S/cm, and from 5.44 μV/K to ~16.0 μV/K at ~300 K, respectively, when compared to the PPy/paper TE nanocomposite films. The thermal conductivity of the PEDOT:PSS/PPy/paper composite film (0.1522 WmK at ~300 K) was, however, only slightly higher than that of the PPy/paper composite film (0.1142 WmK at ~300 K). As a result, the value of the PEDOT:PSS/PPy/paper composite film (1.85 × 10 at 300 K) was significantly enhanced when compared to that of the PPy/paper composite film (4.73 × 10 at ~300 K). The as-prepared nanocomposite films have great potential for application in flexible TE devices.

摘要

通过两步法制备了柔性聚（3,4 - 乙撑二氧噻吩）：聚（苯乙烯磺酸盐）/聚吡咯/纸（PEDOT:PSS/PPy/纸）热电（TE）纳米复合薄膜：首先，通过原位化学聚合工艺制备PPy/纸纳米复合薄膜；其次，使用二甲基亚砜掺杂的PEDOT:PSS溶液涂覆所制备的PPy/纸纳米复合薄膜，制备PEDOT:PSS/PPy/纸TE复合薄膜。与PPy/纸TE纳米复合薄膜相比，PEDOT:PSS/PPy/纸TE纳米复合薄膜在约300 K时的电导率和塞贝克系数分别从0.06 S/cm大幅提高到约0.365 S/cm，以及从5.44 μV/K提高到约16.0 μV/K。然而，PEDOT:PSS/PPy/纸复合薄膜在约300 K时的热导率（0.1522 WmK）仅略高于PPy/纸复合薄膜在约300 K时的热导率（0.1142 WmK）。结果，与PPy/纸复合薄膜在约300 K时的值（约4.73×10）相比，PEDOT:PSS/PPy/纸复合薄膜在约300 K时的值（约1.85×）显著提高。所制备的纳米复合薄膜在柔性TE器件中具有巨大的应用潜力。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d1d4/5551823/1bae771f57b4/materials-10-00780-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d1d4/5551823/c57c0cd9c535/materials-10-00780-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d1d4/5551823/9f1e2941e9ca/materials-10-00780-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d1d4/5551823/22ea2de44167/materials-10-00780-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d1d4/5551823/8d0e25f983cb/materials-10-00780-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d1d4/5551823/1bae771f57b4/materials-10-00780-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d1d4/5551823/c57c0cd9c535/materials-10-00780-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d1d4/5551823/9f1e2941e9ca/materials-10-00780-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d1d4/5551823/22ea2de44167/materials-10-00780-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d1d4/5551823/8d0e25f983cb/materials-10-00780-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d1d4/5551823/1bae771f57b4/materials-10-00780-g005.jpg

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