Department of Mechanical Engineering, University of Tokyo , 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656, Japan.
Department of Mechanical Engineering, Kyung Hee University , 1732 Deogyoung-daero, Giheung-gu, Yongin-si, Gyeounggi-do 446-701, South Korea.
ACS Appl Mater Interfaces. 2017 Sep 6;9(35):30100-30106. doi: 10.1021/acsami.7b06567. Epub 2017 Aug 22.
The heat flow at the interfaces of complex nanostructures is three-dimensional in part due to the nonplanarity of interfaces. One example common in nanosystems is the situation when a significant fraction of the interfacial area is composed of sidewalls that are perpendicular to the principal plane, for example, in metallization structures for complementary metal-oxide semiconductor transistors. It is often observed that such sidewall interfaces contain significantly higher levels of microstructural disorder, which impedes energy carrier transport and leads to effective increases in interfacial resistance. The impact of these sidewall interfaces needs to be explored in greater depth for practical device engineering, and a related problem is that appropriate characterization techniques are not available. Here, we develop a novel electrothermal method and an intricate microfabricated structure to extract the thermal resistance of a sidewall interface between aluminum and silicon dioxide using suspended nanograting structures. The thermal resistance of the sidewall interface is measured to be ∼16 ± 5 m K GW, which is twice as large as the equivalent horizontal planar interface comprising the same materials in the experimental sample. The rough sidewall interfaces are observed using transmission electron micrographs, which may be more extensive than at interfaces in the substrate plan in the same nanostructure. A model based on a two-dimensional sinusoidal surface estimates the impact of the roughness on thermal resistance to be ∼2 m K GW. The large disparity between the model predictions and the experiments is attributed to the incomplete contact at the Al-SiO sidewall interfaces, inferred by observation of underetching of the silicon substrate below the sidewall opening. This study suggests that sidewall interfaces must be considered separately from planar interfaces in thermal analysis for nanostructured systems.
复杂纳米结构界面处的热流在部分情况下是三维的,这是由于界面的非平面性所致。纳米系统中常见的一个例子是,当很大一部分界面面积由垂直于主平面的侧壁组成时,例如互补金属氧化物半导体晶体管的金属化结构。人们经常观察到,这种侧壁界面包含明显更高水平的微观结构无序,这阻碍了能量载体的传输,并导致界面电阻的有效增加。为了实际的器件工程,需要更深入地研究这些侧壁界面的影响,而一个相关的问题是,没有可用的适当表征技术。在这里,我们开发了一种新颖的电热方法和一种复杂的微加工结构,使用悬浮纳米光栅结构来提取铝和二氧化硅之间的侧壁界面的热阻。测量到侧壁界面的热阻约为 16 ± 5 m K GW,是实验样品中相同材料的等效水平平面界面的两倍。通过透射电子显微镜观察到粗糙的侧壁界面,其可能比同一纳米结构中衬底平面上的界面更广泛。基于二维正弦曲面的模型估计,粗糙度对热阻的影响约为 2 m K GW。模型预测与实验之间的巨大差异归因于在侧壁开口下方的硅衬底的过蚀刻观察到的 Al-SiO 侧壁界面不完全接触。这项研究表明,在对纳米结构系统进行热分析时,必须将侧壁界面与平面界面分别考虑。