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含肟基有机凝胶对有机磷化合物的检测与修复

Detection and remediation of organophosphorus compounds by oximate containing organogels.

作者信息

Hiscock Jennifer R, Sambrook Mark R, Wells Neil J, Gale Philip A

机构信息

Chemistry , University of Southampton , Highfield , Southampton , England SO17 1BJ , UK . Email:

CBR Division , Dstl Porton Down , Salisbury , Wiltshire SP4 0JQ , UK . Email:

出版信息

Chem Sci. 2015 Oct 1;6(10):5680-5684. doi: 10.1039/c5sc01864a. Epub 2015 Jul 10.

DOI:10.1039/c5sc01864a
PMID:28791084
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC5527500/
Abstract

A series of supramolecular diamide organogels containing a reactive compound for the remediation of organophosphorus (OP) species, in particular OP chemical warfare agents (CWAs), has been prepared in DMSO. The organogels have been found to absorb, encapsulate and decontaminate various OP CWA simulants . At high simulant concentrations the gels also undergo a gel-sol transition releasing high local concentrations of remediation agent.

摘要

在二甲基亚砜(DMSO)中制备了一系列含有用于修复有机磷(OP)物质,特别是OP化学战剂(CWA)的反应性化合物的超分子二酰胺有机凝胶。已发现这些有机凝胶能吸收、封装并净化各种OP CWA模拟物。在高模拟物浓度下,凝胶还会发生凝胶-溶胶转变,释放出高局部浓度的修复剂。

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