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利用表面等离子体共振(SPR)的纳米传感与能量转换

Nano Sensing and Energy Conversion Using Surface Plasmon Resonance (SPR).

作者信息

Kim Iltai Isaac, Kihm Kenneth David

机构信息

School of Engineering and Computing Science, Texas A&M University-Corpus Christi, 6300 Ocean Drive Unit 5797, Corpus Christi, TX 78412, USA.

Department of Mechanical, Aerospace, and Biomedical Engineering, University of Tennessee, 408 Dougherty Hall, Knoxville, TN 37996-2210, USA.

出版信息

Materials (Basel). 2015 Jul 16;8(7):4332-4343. doi: 10.3390/ma8074332.

Abstract

Nanophotonic technique has been attracting much attention in applications of nano-bio-chemical sensing and energy conversion of solar energy harvesting and enhanced energy transfer. One approach for nano-bio-chemical sensing is surface plasmon resonance (SPR) imaging, which can detect the material properties, such as density, ion concentration, temperature, and effective refractive index in high sensitivity, label-free, and real-time under ambient conditions. Recent study shows that SPR can successfully detect the concentration variation of nanofluids during evaporation-induced self-assembly process. Spoof surface plasmon resonance based on multilayer metallo-dielectric hyperbolic metamaterials demonstrate SPR dispersion control, which can be combined with SPR imaging, to characterize high refractive index materials because of its exotic optical properties. Furthermore, nano-biophotonics could enable innovative energy conversion such as the increase of absorption and emission efficiency and the perfect absorption. Localized SPR using metal nanoparticles show highly enhanced absorption in solar energy harvesting. Three-dimensional hyperbolic metamaterial cavity nanostructure shows enhanced spontaneous emission. Recently ultrathin film perfect absorber is demonstrated with the film thickness is as low as ~1/50th of the operating wavelength using epsilon-near-zero (ENZ) phenomena at the wavelength close to SPR. It is expected to provide a breakthrough in sensing and energy conversion applications using the exotic optical properties based on the nanophotonic technique.

摘要

纳米光子技术在纳米生化传感、太阳能收集的能量转换以及增强能量转移等应用中一直备受关注。纳米生化传感的一种方法是表面等离子体共振(SPR)成像,它能够在环境条件下,以高灵敏度、无标记且实时的方式检测材料特性,如密度、离子浓度、温度和有效折射率。最近的研究表明,SPR能够在蒸发诱导自组装过程中成功检测纳米流体的浓度变化。基于多层金属 - 电介质双曲超材料的类表面等离子体共振展现出SPR色散控制,由于其独特的光学特性,它可以与SPR成像相结合,用于表征高折射率材料。此外,纳米生物光子学能够实现创新的能量转换,例如提高吸收和发射效率以及实现完美吸收。使用金属纳米颗粒的局域表面等离子体共振在太阳能收集方面表现出高度增强的吸收。三维双曲超材料腔纳米结构显示出自发发射增强。最近,利用在接近SPR波长处的近零介电常数(ENZ)现象,展示了薄膜厚度低至约工作波长1/50的超薄完美吸收体。预计基于纳米光子技术的独特光学特性,它将在传感和能量转换应用中带来突破。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a085/5455621/13cd50bfff95/materials-08-04332-g001.jpg

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