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非相干散射可以在纳米结构热电材料中对能量过滤产生有利影响。

Incoherent scattering can favorably influence energy filtering in nanostructured thermoelectrics.

机构信息

Department of Electrical Engineering, Indian Institute of Technology Bombay, Powai, Mumbai, 400076, India.

出版信息

Sci Rep. 2017 Aug 11;7(1):7879. doi: 10.1038/s41598-017-07935-w.

Abstract

Investigating in detail the physics of energy filtering through a single planar energy barrier in nanostructured thermoelectric generators, we reinforce the non-trivial result that the anticipated enhancement in generated power at a given efficiency via energy filtering is a characteristic of systems dominated by incoherent scattering and is absent in ballistic devices. In such cases, assuming an energy dependent relaxation time τ(E) = kE , we show that there exists a minimum value r beyond which generation can be enhanced by embedding nanobarriers. For bulk generators with embedded nanobarriers, we delve into the details of inter sub-band scattering and show that it has finite contribution to the enhancement in generation. We subsequently discuss the realistic aspects, such as the effect of smooth transmission cut-off and show that for r > r , the optimized energy barrier is just sufficiently wide enough to scatter off low energy electrons, a very wide barrier being detrimental to the performance. Analysis of the obtained results should provide general design guidelines for enhancement in thermoelectric generation via energy filtering. Our non-equilibrium approach is typically valid in the absence of local quasi-equilibrium and hence sets the stage for future advancements in thermoelectric device analysis, for example, Peltier cooling near a barrier interface.

摘要

详细研究了在纳米结构热电器件中单平面能垒中通过能量过滤的物理性质,我们强化了一个非平凡的结果,即在给定效率下通过能量过滤预期的发电功率增强是由非相干散射主导的系统的特征,在弹道器件中不存在。在这种情况下,假设能量依赖的弛豫时间τ(E) = kE ,我们表明,存在一个最小值 r ,超过该值后,通过嵌入纳米势垒可以增强发电。对于嵌入纳米势垒的体热电器件,我们深入研究了子带间散射的细节,并表明它对发电增强有有限的贡献。我们随后讨论了实际方面,例如平滑传输截止的影响,并表明对于 r > r ,优化的能垒只是足够宽,足以散射低能电子,过宽的势垒会对性能造成损害。对所得到的结果的分析应该为通过能量过滤增强热发电提供一般的设计指南。我们的非平衡方法通常在不存在局部准平衡的情况下有效,因此为热电器件分析的未来发展奠定了基础,例如在势垒界面附近的珀耳帖冷却。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b328/5554188/bbfe3f516747/41598_2017_7935_Fig1_HTML.jpg

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