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在纳米结构金属氧化物薄膜上,黄素光氧化催化剂氧化烷基苯。

Oxidation of alkyl benzenes by a flavin photooxidation catalyst on nanostructured metal-oxide films.

机构信息

Department of Chemistry, University of North Carolina at Chapel Hill, Chapel Hill, NC 27599.

Department of Chemistry, University of North Carolina at Chapel Hill, Chapel Hill, NC 27599

出版信息

Proc Natl Acad Sci U S A. 2017 Aug 29;114(35):9279-9283. doi: 10.1073/pnas.1707318114. Epub 2017 Aug 11.

Abstract

We describe here a surface-bound, oxide-based procedure for the photooxidation of a family of aromatic hydrocarbons by a phosphate-bearing flavin mononucleotide (FMN) photocatalyst on high surface area metal-oxide films.

摘要

我们在这里描述了一种基于表面结合的氧化方法,通过在高表面积金属氧化物薄膜上带有磷酸盐的黄素单核苷酸 (FMN) 光催化剂来光氧化一系列芳香烃。

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