铈催化苄醇有氧氧化制备醛和酮
Cerium-photocatalyzed aerobic oxidation of benzylic alcohols to aldehydes and ketones.
作者信息
Yedase Girish Suresh, Kumar Sumit, Stahl Jessica, König Burkhard, Yatham Veera Reddy
机构信息
School of Chemistry, Indian Institute of Science Education and Research, Thiruvananthapuram (IISER-TVM) 695551, India.
Institut für Organische Chemie, Fakultät für Chemie und Pharmazie, Universität Regensburg, Universitätstraße 31, D-93053 Regensburg, Germany.
出版信息
Beilstein J Org Chem. 2021 Jul 23;17:1727-1732. doi: 10.3762/bjoc.17.121. eCollection 2021.
Abstract
We have developed a cerium-photocatalyzed aerobic oxidation of primary and secondary benzylic alcohols to aldehydes and ketones using inexpensive CeCl·7HO as photocatalyst and air oxygen as the terminal oxidant.
摘要
我们已经开发出一种铈光催化的一级和二级苄醇有氧氧化反应，该反应以廉价的CeCl₃·7H₂O作为光催化剂，以空气中的氧气作为终端氧化剂，将苄醇氧化为醛和酮。
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