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多壁碳纳米管(MWCNTs)增强纳米复合材料的动态行为

Dynamic Behavior of Nanocomposites Reinforced with Multi-Walled Carbon Nanotubes (MWCNTs).

作者信息

Her Shiuh-Chuan, Lai Chun-Yu

机构信息

Department of Mechanical Engineering, Yuan Ze University, 135 Yuan-Tung Road, Chung-Li 320, Taiwan.

出版信息

Materials (Basel). 2013 Jun 3;6(6):2274-2284. doi: 10.3390/ma6062274.

DOI:10.3390/ma6062274
PMID:28809273
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC5458950/
Abstract

The influence of multi-walled carbon nanotubes (MWCNT) on the structural dynamic behavior of MWCNT/epoxy nanocomposites was investigated. Two different types of MWCNTs, pristine MWCNT and functionalized MWCNT, were used in this study. Carboxylic acid-functionalized MWCNTs (MWCNT-COOH) were obtained by oxidation pristine MWCNTs via sonication in sulfuric-nitric acid and characterized by Fourier transform infrared spectroscopy (FTIR). Dynamic behaviors of the MWCNT reinforced nanocomposite including the natural frequency and damping ratio were determined using free vibration test. Experimental results showed that the damping ratio of the nanocomposite decreases with the increase of the MWCNT addition, while the natural frequency is increasing with the increase of the MWCNT addition. Functionalized MWCNTs improved the interfacial bonding between the nanotubes and epoxy resin resulting in the reduction of the interfacial energy dissipation ability and enhancement of the stiffness.

摘要

研究了多壁碳纳米管(MWCNT)对MWCNT/环氧树脂纳米复合材料结构动力学行为的影响。本研究使用了两种不同类型的MWCNT,即原始MWCNT和功能化MWCNT。通过在硫酸-硝酸中超声处理氧化原始MWCNT获得了羧酸功能化的MWCNT(MWCNT-COOH),并通过傅里叶变换红外光谱(FTIR)对其进行了表征。使用自由振动试验测定了MWCNT增强纳米复合材料的动力学行为,包括固有频率和阻尼比。实验结果表明,纳米复合材料的阻尼比随着MWCNT添加量的增加而降低,而固有频率则随着MWCNT添加量的增加而增加。功能化MWCNT改善了纳米管与环氧树脂之间的界面结合,导致界面能量耗散能力降低和刚度增强。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4abc/5458950/2323621d4beb/materials-06-02274-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4abc/5458950/ca95df898bf5/materials-06-02274-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4abc/5458950/8fc3a64fdec0/materials-06-02274-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4abc/5458950/03ac8e77b92f/materials-06-02274-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4abc/5458950/318115b8d453/materials-06-02274-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4abc/5458950/6d01005dafdd/materials-06-02274-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4abc/5458950/e7a78694a48c/materials-06-02274-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4abc/5458950/2323621d4beb/materials-06-02274-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4abc/5458950/ca95df898bf5/materials-06-02274-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4abc/5458950/8fc3a64fdec0/materials-06-02274-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4abc/5458950/03ac8e77b92f/materials-06-02274-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4abc/5458950/318115b8d453/materials-06-02274-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4abc/5458950/6d01005dafdd/materials-06-02274-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4abc/5458950/e7a78694a48c/materials-06-02274-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4abc/5458950/2323621d4beb/materials-06-02274-g007.jpg

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