被亲氧锗烯和亚锡烯配体捕获的一氧化锗和一氧化锡
Germanium and Tin Monoxides Trapped by Oxophilic Germylene and Stannylene Ligands.
作者信息
Gao Yunxia, Yang Ying, Zheng Wenjun, Su Yuanyuan, Zhang Xiang, Roesky Herbert W
机构信息
Institute of Organic Chemistry & College of Chemical and Materials Science & Key Laboratory of Magnetic Molecules and Magnetic Information Materials, Ministry of Education, Shanxi Normal University , Gongyuan Street 1, Linfen, Shanxi Province, 041004, People's Republic of China.
School of Chemistry and Chemical Engineering, Central South University , Lushannan Road 932, Changsha, Hunan Province 410083, People's Republic of China.
出版信息
Inorg Chem. 2017 Sep 5;56(17):10220-10225. doi: 10.1021/acs.inorgchem.7b00918. Epub 2017 Aug 16.
Germanium and tin monoxides (MO, M = Ge, Sn) were trapped by the 1,2,4-diazaphospholide-based germylene and stannylene M[3,5-tBudp] (M = Ge (2), Sn (3)), resulting in the Lewis acid-base adduct of composition M(μ-O)[M{η(N)-(3,5-tBudp)}] (M = Ge (4), Sn (5)). Compounds 4 and 5 were characterized by single-crystal X-ray structural analysis. The bonding features of 4 and 5 were supported by DFT calculations.
一氧化锗和一氧化锡（MO，M = Ge，Sn）被基于1,2,4 - 二氮磷杂环戊二烯的锗烯和锡烯M[3,5 - tBu₂dp]（M = Ge (2)，Sn (3)）捕获，生成了组成式为M(μ - O)[M{η(N)-(3,5 - tBu₂dp)}]的路易斯酸碱加合物（M = Ge (4)，Sn (5)）。化合物4和5通过单晶X射线结构分析进行了表征。4和5的键合特征得到了密度泛函理论（DFT）计算的支持。
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