α-重氮-β-羟基酮的重排在双环[m.n.1]烷酮合成中的应用。
Rearrangements of α-Diazo-β-hydroxyketones for the Synthesis of Bicyclo[m.n.1]alkanones.
机构信息
Department of Chemistry and State Key Laboratory of Synthetic Chemistry, The University of Hong Kong , Pokfulam Road, Hong Kong, P. R. China.
出版信息
Org Lett. 2017 Sep 1;19(17):4464-4467. doi: 10.1021/acs.orglett.7b01963. Epub 2017 Aug 22.
PMID:28829145
Abstract
Rhodium-catalyzed decomposition of fused bicyclic α-diazo-β-hydroxyketones results in good yields of bridged bicyclo[m.n.1]ketones via a rearrangement pathway.
摘要
铑催化的稠合双环 α-重氮-β-羟基酮的分解反应通过重排途径得到桥连双环[m.n.1]酮，产率良好。
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