Advanced Computing and Simulation Laboratory (AχL), Department of Electrical and Computer Systems Engineering, Monash University, Clayton, Victoria 3800, Australia.
Jet Propulsion Laboratory, California Institute of Technology, Pasadena, California 91109, USA.
J Chem Phys. 2017 Aug 21;147(7):074117. doi: 10.1063/1.4998459.
The ability to control light-matter interactions in quantum objects opens up many avenues for new applications. We look at this issue within a fully quantized framework using a fundamental theory to describe mirror-assisted resonance energy transfer (RET) in nanostructures. The process of RET communicates electronic excitation between suitably disposed donor and acceptor particles in close proximity, activated by the initial excitation of the donor. Here, we demonstrate that the energy transfer rate can be significantly controlled by careful positioning of the RET emitters near a mirror. The results deliver equations that elicit new insights into the associated modification of virtual photon behavior, based on the quantum nature of light. In particular, our results indicate that energy transfer efficiency in nanostructures can be explicitly expedited or suppressed by a suitably positioned neighboring mirror, depending on the relative spacing and the dimensionality of the nanostructure. Interestingly, the resonance energy transfer between emitters is observed to "switch off" abruptly under suitable conditions of the RET system. This allows one to quantitatively control RET systems in a new way.
在量子物体中控制光物质相互作用的能力为许多新的应用开辟了道路。我们在一个完全量子化的框架内使用一种基本理论来研究这个问题,该理论描述了纳米结构中的镜像辅助共振能量转移(RET)。RET 过程在适当放置的供体和受体粒子之间传递电子激发,通过供体的初始激发来激活。在这里,我们证明通过仔细定位 RET 发射器靠近镜子,可以显著控制能量转移速率。这些结果提供了一些方程,根据光的量子性质,这些方程引出了对相关虚拟光子行为修饰的新见解。特别是,我们的结果表明,在适当的相邻镜位置下,根据纳米结构的相对间距和维度,可以明确地加速或抑制纳米结构中的能量转移效率。有趣的是,在 RET 系统的适当条件下,发射器之间的共振能量转移被观察到突然“关闭”。这使得人们可以以新的方式定量控制 RET 系统。