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用于一氧化碳还原和水氧化的钌催化剂的策略性设计:共配体的电子影响

Strategic design of a ruthenium catalyst for both CO reduction and HO oxidation: the electronic influence of the co-ligands.

作者信息

Das Biswanath, Ezzedinloo Lida, Bhadbhade Mohan, Bucknall Martin P, Colbran Stephen B

机构信息

School of Chemistry, The University of New South Wales, Sydney, NSW 2052, Australia.

出版信息

Chem Commun (Camb). 2017 Sep 5;53(72):10006-10009. doi: 10.1039/c7cc06294j.

Abstract

A new ruthenium(ii) complex capable of catalysing both CO reduction and water oxidation was designed and synthesised. The electro-catalytic efficiency and robustness of the complex together with the electronic effect of its co-ligands were investigated to develop next generation dual activity electrocatalysts.

摘要

设计并合成了一种能够催化一氧化碳还原和水氧化的新型钌(II)配合物。研究了该配合物的电催化效率、稳定性及其共配体的电子效应,以开发下一代双活性电催化剂。

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