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基于配体截断策略的高性能气体吸附与分离微孔金属有机框架

Microporous Metal-Organic Framework Based on Ligand-Truncation Strategy with High Performance for Gas Adsorption and Separation.

作者信息

Liu Jianqiang, Wang Wenjing, Luo Zhidong, Li Baohong, Yuan Daqiang

机构信息

School of Pharmacy, Guangdong Medical University , Dongguan 523808, China.

State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences , Fuzhou 350002, China.

出版信息

Inorg Chem. 2017 Sep 5;56(17):10215-10219. doi: 10.1021/acs.inorgchem.7b00851. Epub 2017 Aug 24.

DOI:10.1021/acs.inorgchem.7b00851
PMID:28837334
Abstract

By using the ligand-truncation strategy, a microporous metal-organic framework (1) with high surface area was designedly synthesized. MOF 1 shows a new (4, 4)-connected net with a Schläfli symbol of (4.6)(4.6.8)(4.8.10) and exhibits a high H capture capacity (193 cm g at 1 atm and 77 K) and selectivities for CO over N and CH at low pressure.

摘要

通过采用配体截断策略，设计合成了一种具有高比表面积的微孔金属有机框架材料（1）。金属有机框架材料1呈现出一种新的（4,4）连接网络，其施莱夫利符号为（4.6）（4.6.8）（4.8.10），并且在1个大气压和77K条件下表现出高氢气捕获容量（193 cm³/g）以及在低压下对一氧化碳相对于氮气和甲烷的选择性。

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