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三维石墨烯与 MoS 纳米杂化作为潜在的能量存储/传输器件。

Three-dimensional Graphene with MoS Nanohybrid as Potential Energy Storage/Transfer Device.

机构信息

Institute of Nano Science and Technology, Sec. 64, Mohali, Punjab, India.

出版信息

Sci Rep. 2017 Aug 25;7(1):9458. doi: 10.1038/s41598-017-09266-2.

Abstract

Portable and matured energy storage devices are in high demand for future flexible electronics. Flowery shaped MoS nanostructures with porous and flake like morphology was used to study the supercapacitive nature with specific capacitance (C ) of 169.37F/g, the energy density of 28.43 Wh/Kg and power density of 10.18 W/Kg. This nanoflower like architecture was decorated on 3D-graphene on Graphite electrode to design the solid-state-supercapacitor prototype device of dimensions of 23.6 × 22.4 × 0.6 mm having considerable high Csp of 58.0F/g and energy density of 24.59 Wh/Kg, and power density of 8.8 W/Kg. Four fabricated supercapacitors were connected in series for real state practical demonstration using the light emitting diode that remains enlightened for 40 s by charging it only for 25 s. This study demonstrates the 3D-graphene/MoS nanohybrid has a quite high overall potential window nearly about 2.7 V (-1.5 to +1.2 V) in KOH-PVA medium which can be used for the development of solid-state supercapacitors thereby completely eliminating the need for any expensive ionic liquid mediums thus building an exciting potential for high-performance energy storage/transfer devices.

摘要

对于未来的柔性电子产品,人们对便携式和成熟的储能设备有很高的需求。采用具有多孔和片状形态的花状 MoS 纳米结构来研究超级电容器的性质,比电容 (C ) 为 169.37F/g,能量密度为 28.43 Wh/Kg,功率密度为 10.18 W/Kg。这种纳米花状结构被装饰在 3D 石墨烯上,用于设计尺寸为 23.6×22.4×0.6mm 的固态超级电容器原型器件,具有相当高的比电容 (Csp) 58.0F/g 和能量密度 24.59 Wh/Kg,功率密度 8.8 W/Kg。四个制造的超级电容器串联用于实际状态的实际演示,使用发光二极管,仅充电 25 秒即可持续照明 40 秒。这项研究表明,3D 石墨烯/MoS 纳米杂化材料在 KOH-PVA 介质中具有相当高的整体电位窗口,接近 2.7V(-1.5 至 +1.2V),可用于开发固态超级电容器,从而完全消除对任何昂贵的离子液体介质的需求,从而为高性能储能/传输设备的发展带来了令人兴奋的潜力。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c0dd/5573343/be93515b7e24/41598_2017_9266_Fig1_HTML.jpg

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