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用于高性能储能应用的碳基聚合物纳米复合材料。

Carbon-Based Polymer Nanocomposite for High-Performance Energy Storage Applications.

作者信息

Siwal Samarjeet Singh, Zhang Qibo, Devi Nishu, Thakur Vijay Kumar

机构信息

Key Laboratory of Ionic Liquids Metallurgy, Faculty of Metallurgical and Energy Engineering, Kunming University of Science and Technology, Kunming 650093, China.

State Key Laboratory of Complex Nonferrous Metal Resources Cleaning Utilization in Yunnan Province, Kunming 650093, China.

出版信息

Polymers (Basel). 2020 Feb 26;12(3):505. doi: 10.3390/polym12030505.

Abstract

In recent years, numerous discoveries and investigations have been remarked for the development of carbon-based polymer nanocomposites. Carbon-based materials and their composites hold encouraging employment in a broad array of fields, for example, energy storage devices, fuel cells, membranes sensors, actuators, and electromagnetic shielding. Carbon and its derivatives exhibit some remarkable features such as high conductivity, high surface area, excellent chemical endurance, and good mechanical durability. On the other hand, characteristics such as docility, lower price, and high environmental resistance are some of the unique properties of conducting polymers (CPs). To enhance the properties and performance, polymeric electrode materials can be modified suitably by metal oxides and carbon materials resulting in a composite that helps in the collection and accumulation of charges due to large surface area. The carbon-polymer nanocomposites assist in overcoming the difficulties arising in achieving the high performance of polymeric compounds and deliver high-performance composites that can be used in electrochemical energy storage devices. Carbon-based polymer nanocomposites have both advantages and disadvantages, so in this review, attempts are made to understand their synergistic behavior and resulting performance. The three electrochemical energy storage systems and the type of electrode materials used for them have been studied here in this article and some aspects for example morphology, exterior area, temperature, and approaches have been observed to influence the activity of electrochemical methods. This review article evaluates and compiles reported data to present a significant and extensive summary of the state of the art.

摘要

近年来,碳基聚合物纳米复合材料的发展取得了众多发现和研究成果。碳基材料及其复合材料在广泛的领域有着令人鼓舞的应用,例如储能装置、燃料电池、膜传感器、致动器和电磁屏蔽。碳及其衍生物具有一些显著特性,如高导电性、高表面积、出色的化学耐受性和良好的机械耐久性。另一方面,柔顺性、较低价格和高环境耐受性等特性是导电聚合物(CPs)的一些独特性能。为了提高性能,聚合物电极材料可以用金属氧化物和碳材料进行适当改性,从而形成一种复合材料,由于其大表面积有助于电荷的收集和积累。碳 - 聚合物纳米复合材料有助于克服在实现聚合物化合物高性能方面出现的困难,并提供可用于电化学储能装置的高性能复合材料。碳基聚合物纳米复合材料既有优点也有缺点,因此在本综述中,试图了解它们的协同行为和由此产生的性能。本文研究了三种电化学储能系统以及用于它们的电极材料类型,并观察到一些方面,例如形态、表面积、温度和方法,会影响电化学方法的活性。这篇综述文章评估并汇编了已报道的数据,以呈现该领域的重要且全面的现状总结。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/39c0/7182882/cd4f8ad49012/polymers-12-00505-g001.jpg

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