Department of Chemistry, University of Washington, Box 351700, Seattle, Washington, 98195-1700, USA.
Small. 2017 Oct;13(40). doi: 10.1002/smll.201702038. Epub 2017 Aug 30.
II V semiconductors have become increasingly popular for a variety of applications including solar light harvesting, near-IR imaging, and low energy light detection. The bulk physical and electronic structure of these materials is highlighted, followed by an in-depth survey on progress in synthesizing these semiconductors as colloidal nanocrystals. Interestingly, no universal synthetic approach has yet been developed to access all compounds within this family. A discussion on how the complex crystal structure of these materials translates to small domain sizes will highlight current challenges in the characterization of II V nanocrystals. Finally, potential avenues for further research will be proposed as a way to advance this field towards greater utilization in light harvesting applications.
II-V 族半导体由于在各种应用中的普及而受到越来越多的关注,包括太阳能采集、近红外成像和低能量光探测。本文重点介绍了这些材料的体物理和电子结构,然后深入调查了作为胶体纳米晶体合成这些半导体的进展。有趣的是,目前还没有一种通用的合成方法来获得该族中的所有化合物。讨论这些材料的复杂晶体结构如何转化为小的畴尺寸,将突出当前在 II-V 纳米晶体表征方面的挑战。最后,提出了进一步研究的潜在途径,以推动该领域在光收集应用中得到更广泛的利用。