在卤键超分子网络辅助下铁配合物的光致可逆自旋态切换
Photoinduced reversible spin-state switching of an Fe complex assisted by a halogen-bonded supramolecular network.
作者信息
Jeon Ie-Rang, Mathonière Corine, Clérac Rodolphe, Rouzières Mathieu, Jeannin Olivier, Trzop Elzbieta, Collet Eric, Fourmigué Marc
机构信息
Institut des Sciences Chimiques de Rennes, Université de Rennes 1 & CNRS UMR 6226, Campus Beaulieu, 35042 Rennes, France.
出版信息
Chem Commun (Camb). 2017 Sep 14;53(74):10283-10286. doi: 10.1039/c7cc03797j.
The organization of a molecular Fe complex embedded in a halogen-bonded 2D network is chemically tuned to trigger temperature- and light-induced spin-state switching. We attribute the associated magnetic properties and the unprecedented photoswitching effect to the optimized structural confinement provided by the presence of the supramolecular host framework.
嵌入卤键二维网络中的分子铁配合物的结构通过化学调控，以触发温度和光诱导的自旋态切换。我们将相关的磁性和前所未有的光开关效应归因于超分子主体框架的存在所提供的优化结构限制。
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