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任务特定离子液体在生物样品和金属离子手性拆分与萃取中的最新进展。

Recent progress of task-specific ionic liquids in chiral resolution and extraction of biological samples and metal ions.

机构信息

Advanced Catalysis and Green Manufacturing Collaborative Innovation Center, Changzhou University, Changzhou, China.

Department of Chemistry, Zhejiang University, Hangzhou, China.

出版信息

J Sep Sci. 2018 Jan;41(1):373-384. doi: 10.1002/jssc.201700848. Epub 2017 Sep 28.

DOI:10.1002/jssc.201700848
PMID:28876511
Abstract

Ionic liquids have been functionalized for modern applications. The functional ionic liquids are also called task-specific ionic liquids. Various task-specific ionic liquids with certain groups have been constructed and exploited widely in the field of separation. To take advantage of their properties in separation science, task-specific ionic liquids are generally used in techniques such as liquid-liquid extraction, solid-phase extraction, gas chromatography, high-performance liquid chromatography, and capillary electrophoresis. This review mainly covers original research papers published in the last five years, and we will focus on task-specific ionic liquids as the chiral selectors in chiral resolution and as extractant or sensor for biological samples and metal ion purification.

摘要

离子液体已经实现了功能化,以满足现代应用的需求。功能化离子液体也被称为特定任务离子液体。各种具有特定基团的特定任务离子液体已经被构建,并广泛应用于分离领域。为了利用它们在分离科学中的特性,特定任务离子液体通常用于液-液萃取、固相萃取、气相色谱、高效液相色谱和毛细管电泳等技术中。本综述主要涵盖了过去五年发表的原创研究论文,我们将重点关注特定任务离子液体作为手性拆分中的手性选择剂,以及作为生物样品和金属离子纯化的萃取剂或传感器。

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Recent progress of task-specific ionic liquids in chiral resolution and extraction of biological samples and metal ions.任务特定离子液体在生物样品和金属离子手性拆分与萃取中的最新进展。
J Sep Sci. 2018 Jan;41(1):373-384. doi: 10.1002/jssc.201700848. Epub 2017 Sep 28.
2
Future of Ionic Liquids for Chiral Separations in High-Performance Liquid Chromatography and Capillary Electrophoresis.离子液体在高效液相色谱和毛细管电泳手性分离中的未来。
Crit Rev Anal Chem. 2019;49(4):289-305. doi: 10.1080/10408347.2018.1523706. Epub 2018 Dec 24.
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Recent advances in the enantioseparation promoted by ionic liquids and their resolution mechanisms.离子液体促进对映体分离的最新进展及其拆分机制。
J Chromatogr A. 2020 Aug 30;1626:461384. doi: 10.1016/j.chroma.2020.461384. Epub 2020 Jul 1.
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Chiral Ionic Liquids: Structural Diversity, Properties and Applications in Selected Separation Techniques.手性离子液体:结构多样性、性质及在特定分离技术中的应用。
Int J Mol Sci. 2020 Jun 15;21(12):4253. doi: 10.3390/ijms21124253.
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Chiral ionic liquids in chromatographic and electrophoretic separations.手性离子液体在色谱和电泳分离中的应用。
J Chromatogr A. 2014 Oct 10;1363:2-10. doi: 10.1016/j.chroma.2014.05.059. Epub 2014 May 28.
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Combination of Cyclodextrin and Ionic Liquid in Analytical Chemistry: Current and Future Perspectives.环糊精和离子液体在分析化学中的组合:现状和未来展望。
Crit Rev Anal Chem. 2017 Sep 3;47(5):454-467. doi: 10.1080/10408347.2017.1320936. Epub 2017 Apr 28.
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High resolution of racemic phenylalanine with dication imidazolium-based chiral ionic liquids in a solid-liquid two-phase system.在固液两相体系中,使用基于咪唑鎓二价阳离子的手性离子液体对消旋苯丙氨酸进行高分辨率分离。
J Chromatogr A. 2017 Jan 6;1479:48-54. doi: 10.1016/j.chroma.2016.12.012. Epub 2016 Dec 8.
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Enantioseparation by Capillary Electrophoresis Using Ionic Liquids as Chiral Selectors.手性选择剂离子液体在毛细管电泳中的对映体分离。
Crit Rev Anal Chem. 2018 Nov 2;48(6):429-446. doi: 10.1080/10408347.2018.1439365. Epub 2018 Apr 11.
9
Natural terpene derivatives as new structural task-specific ionic liquids to enhance the enantiorecognition of acidic enantiomers on teicoplanin-based stationary phase by high-performance liquid chromatography.天然萜烯衍生物作为新型结构的任务特定离 子液体,通过高效液相色谱法增强基于替考拉宁的固定相上酸性对映异构体的对映体识别。
J Sep Sci. 2017 Jun;40(11):2374-2381. doi: 10.1002/jssc.201700197. Epub 2017 May 8.
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Dispersive solid-phase extraction of racemic drugs using chiral ionic liquid-metal-organic framework composite sorbent.手性离子液体-金属有机骨架复合材料吸附剂用于对映体药物的分散固相萃取。
J Chromatogr A. 2020 Sep 13;1627:461395. doi: 10.1016/j.chroma.2020.461395. Epub 2020 Jul 6.

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