Key Laboratory of Functional Molecular Engineering of Guangdong Province, School of Chemistry and Chemical Engineering, South China University of Technology , Guangzhou 510640, China.
J Org Chem. 2017 Oct 20;82(20):10912-10919. doi: 10.1021/acs.joc.7b01729. Epub 2017 Oct 9.
An efficient and practical protocol for the synthesis of (E)-allylethers from readily available olefins with alcohols or phenols was developed. This aerobic oxidative allylic C-H oxygenation protocol features mild conditions, broad substrate scope, and high atom and step economy, making it a valuable and convenient synthetic method. Notably, molecular oxygen is the sole oxidant in this novel transformation.
开发了一种从易得的烯烃与醇或酚合成（E）-烯丙基醚的高效实用的方法。该有氧氧化烯丙位 C-H 氧化的反应条件温和、底物范围广泛、原子经济性和步骤经济性高，是一种很有价值和方便的合成方法。值得注意的是，在这种新的转化中，氧气是唯一的氧化剂。
