Yan Y, Rentsch D, Battaglia C, Remhof A
Center for Materials Crystallography, Interdisciplinary Nanoscience Center (iNANO), and Department of Chemistry, Aarhus University, Langelandsgade 140, DK-8000 Aarhus C, Denmark.
Dalton Trans. 2017 Sep 26;46(37):12434-12437. doi: 10.1039/c7dt02946b.
This communication presents the first synthesis of nanoconfined Lithium closo-borate, LiBH, using nanoporous SiO as scaffold. The yield of LiBH is up to 94 mol%. The as-synthesized nanoconfined LiBH exhibits a structural transition around 380 °C and conversion to H-deficiency LiBH at 580 °C.
本通讯介绍了首次以纳米多孔SiO为支架合成纳米受限型closo-硼酸锂LiBH的方法。LiBH的产率高达94摩尔%。合成的纳米受限型LiBH在380℃左右呈现结构转变，并在580℃时转化为缺氢LiBH。
