Interdisciplinary Nanoscience Center (iNANO) and Department of Chemistry, University of Aarhus, DK-8000 Aarhus, Denmark.
Chem Commun (Camb). 2019 Mar 14;55(23):3410-3413. doi: 10.1039/c9cc00187e.
Solvated lithium closo-dodecaborate, Li2B12H12 with tetrahydrofuran and acetonitrile, show unexpected melting below 150 °C. This feature has been explored to melt-infiltrate Li2B12H12 in a nanoporous SiO2 scaffold. The ionic conductivity of Li2B12H12·xACN reaches 0.08 mS cm-1 in the liquid state at 150 °C making them suitable as battery electrolytes.
溶剂化的锂 closo-十二硼烷，Li2B12H12 与四氢呋喃和乙腈，在 150°C 以下表现出异常的熔融。这一特性已被探索用于将 Li2B12H12 熔融渗透到纳米多孔 SiO2 支架中。在 150°C 下，Li2B12H12·xACN 的离子电导率达到 0.08 mS cm-1，使其适合用作电池电解质。
