全合成中季立体中心的构建。
Construction of Quaternary Stereogenic Centers in the Total Synthesis of Natural Products.
机构信息
Department of Medicinal Chemistry, Helmholtz Centre for Infection Research, Inhoffenstrasse 7, 38124, Braunschweig, Germany.
出版信息
Angew Chem Int Ed Engl. 2017 Nov 13;56(46):14356-14358. doi: 10.1002/anie.201706629. Epub 2017 Sep 14.
PMID:28906071
Abstract
Total syntheses of the tetracyclic terpene waihoensene and the densely functionalized tetracyclic compound ryanodol have recently been reported. Both approaches constitute examples of the efficient and innovative construction of multiple quaternary centers.
摘要
最近报道了四环萜类化合物 waihoensene 和高度官能化的四环化合物 ryanodol 的全合成。这两种方法都是高效和创新构建多个季碳原子的例子。
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