连续流动光氧化还原催化实现 CO 促进的苯乙烯的直接 β-选择性氢羧化反应。
Direct β-Selective Hydrocarboxylation of Styrenes with CO Enabled by Continuous Flow Photoredox Catalysis.
机构信息
Department of Chemistry, Massachusetts Institute of Technology , Cambridge, Massachusetts 02139, United States.
出版信息
J Am Chem Soc. 2017 Oct 11;139(40):13969-13972. doi: 10.1021/jacs.7b05942. Epub 2017 Sep 27.
PMID:28953365
Abstract
The direct β-selective hydrocarboxylation of styrenes under atmospheric pressure of CO has been developed using photoredox catalysis in continuous flow. The scope of this methodology was demonstrated with a range of functionalized terminal styrenes, as well as α-substituted and β-substituted styrenes.
摘要
使用光氧化还原催化在连续流中，在大气压 CO 下开发了苯乙烯的直接β选择性加氢羧化反应。该方法的适用范围通过一系列功能化的末端苯乙烯以及α取代和β取代苯乙烯进行了证明。
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