• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利:CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法,用中文像聊天一样搜索,搜遍4000万医学文献。AI智能推荐,让科研检索更轻松。

立即免费搜索

文件翻译

保留排版,准确专业,支持PDF/Word/PPT等文件格式,支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述,25分钟生成高质量综述,智能提取关键信息,辅助科研写作。

立即免费体验

卤键、硫属键、磷键、碲键:起源、现状及讨论。

Halogen bonding, chalcogen bonding, pnictogen bonding, tetrel bonding: origins, current status and discussion.

机构信息

Department of Chemistry, University of Sheffield, Brook Hill S3 7HF, UK.

出版信息

Faraday Discuss. 2017 Oct 13;203:485-507. doi: 10.1039/c7fd00199a.

DOI:10.1039/c7fd00199a
PMID:28980683
Abstract

The role of the closing lecture in a Faraday Discussion is to summarise the contributions made to the Discussion over the course of the meeting and in so doing capture the main themes that have arisen. This article is based upon my Closing Remarks Lecture at the 203 Faraday Discussion meeting on Halogen Bonding in Supramolecular and Solid State Chemistry, held in Ottawa, Canada, on 10-12 July, 2017. The Discussion included papers on fundamentals and applications of halogen bonding in the solid state and solution phase. Analogous interactions involving main group elements outside group 17 were also examined. In the closing lecture and in this article these contributions have been grouped into the four themes: (a) fundamentals, (b) beyond the halogen bond, (c) characterisation, and (d) applications. The lecture and paper also include a short reflection on past work that has a bearing on the Discussion.

摘要

闭幕演讲在 Faraday 讨论中扮演着总结会议过程中做出的贡献,并以此捕捉出现的主要主题的角色。本文基于我在 2017 年 7 月 10 日至 12 日于加拿大渥太华举行的 203 届 Faraday 讨论会上关于超分子和固态化学中卤键的演讲。该讨论包括有关卤键在固态和溶液相中的基础和应用的论文。还研究了涉及第 17 族以外的主族元素的类似相互作用。在闭幕演讲和本文中,这些贡献被分为四个主题:(a)基础,(b)超越卤键,(c)特性,和(d)应用。演讲和论文还包括对过去与讨论有关的工作的简短反思。

相似文献

1
Halogen bonding, chalcogen bonding, pnictogen bonding, tetrel bonding: origins, current status and discussion.卤键、硫属键、磷键、碲键:起源、现状及讨论。
Faraday Discuss. 2017 Oct 13;203:485-507. doi: 10.1039/c7fd00199a.
2
Halogen bonds, chalcogen bonds, pnictogen bonds, tetrel bonds and other σ-hole interactions: a snapshot of current progress.卤键、硫属键、磷属键、拟卤键和其他 σ-空穴相互作用:当前进展概览。
Acta Crystallogr C Struct Chem. 2023 Jun 1;79(Pt 6):204-216. doi: 10.1107/S2053229623004072. Epub 2023 May 22.
3
Halogen, Chalcogen, Pnictogen, and Tetrel Bonding in Non-Covalent Organocatalysis: An Update.非共价有机催化中的卤键、硫族元素键、氮族元素键和碳族元素键:最新进展
Angew Chem Int Ed Engl. 2024 Jul 29;63(31):e202404823. doi: 10.1002/anie.202404823. Epub 2024 Jul 2.
4
Highlights from the Faraday Discussion: Halogen Bonding in Supramolecular and Solid State Chemistry, July 10-12th 2017, Ottawa, Canada.法拉第讨论会亮点:超分子与固态化学中的卤键,2017年7月10日至12日,加拿大渥太华
Chem Commun (Camb). 2017 Oct 24;53(85):11615-11621. doi: 10.1039/c7cc90355c.
5
Concurring Chalcogen- and Halogen-Bonding Interactions in Supramolecular Polymers for Crystal Engineering Applications.用于晶体工程应用的超分子聚合物中同时存在的硫族元素键和卤键相互作用。
Chemistry. 2020 Mar 2;26(13):2904-2913. doi: 10.1002/chem.201904762. Epub 2020 Feb 10.
6
The Chalcogen Bond in Crystalline Solids: A World Parallel to Halogen Bond.晶体固体中的硫族元素键:一个与卤键平行的世界。
Acc Chem Res. 2019 May 21;52(5):1313-1324. doi: 10.1021/acs.accounts.9b00037. Epub 2019 May 13.
7
Catalysis with Pnictogen, Chalcogen, and Halogen Bonds.氮族元素、氧族元素和卤族元素键催化作用
Angew Chem Int Ed Engl. 2018 May 4;57(19):5408-5412. doi: 10.1002/anie.201801452. Epub 2018 Mar 20.
8
Tetrel, pnictogen and chalcogen bonds identified in the gas phase before they had names: a systematic look at non-covalent interactions.在还没有名称之前就在气相中鉴定出的四价元素、氮族元素和氧族元素键:对非共价相互作用的系统研究。
Phys Chem Chem Phys. 2017 Jun 14;19(23):14884-14896. doi: 10.1039/c7cp02518a.
9
Organocatalysis by Halogen, Chalcogen, and Pnictogen Bond Donors in Halide Abstraction Reactions: An Alternative to Hydrogen Bond-Based Catalysis.卤化物、硫族元素和氮族元素键供体在卤化物抽象反应中的有机催化:基于氢键催化的替代方法。
J Phys Chem A. 2020 May 14;124(19):3815-3824. doi: 10.1021/acs.jpca.0c01060. Epub 2020 May 5.
10
Anion Transport with Pnictogen Bonds in Direct Comparison with Chalcogen and Halogen Bonds.与硫属键和卤键直接比较的磷属键阴离子输送。
J Am Chem Soc. 2019 Jan 16;141(2):810-814. doi: 10.1021/jacs.8b12554. Epub 2019 Jan 8.

引用本文的文献

1
The Next Frontier in the Study of Noncovalent Bonding: Transition Metals.非共价键研究的下一个前沿领域:过渡金属。
Molecules. 2025 Sep 7;30(17):3643. doi: 10.3390/molecules30173643.
2
Studying Noncovalent Interactions in Molecular Systems with Machine Learning.利用机器学习研究分子系统中的非共价相互作用。
Chem Rev. 2025 Jun 25;125(12):5776-5829. doi: 10.1021/acs.chemrev.4c00893. Epub 2025 Jun 9.
3
Chalcogenide Materials in Water Purification: Advances in Adsorptive and Photocatalytic Removal of Organic Pollutants.用于水净化的硫族化物材料:有机污染物吸附和光催化去除的进展
Small. 2025 Jul;21(29):e2501378. doi: 10.1002/smll.202501378. Epub 2025 May 28.
4
Taxonomy of Chemical Bondings: Opportunities and Challenges.化学键的分类:机遇与挑战。
Angew Chem Int Ed Engl. 2025 Jul;64(27):e202506525. doi: 10.1002/anie.202506525. Epub 2025 May 22.
5
Unconventional Radical and Radical-Hole Site-Based Interactions in Halogen-Bearing Dimers and Trimers: A Comparative Study.含卤素二聚体和三聚体中基于非常规自由基和自由基-空穴位点的相互作用:一项比较研究。
ACS Omega. 2024 Sep 5;9(37):38743-38752. doi: 10.1021/acsomega.4c04620. eCollection 2024 Sep 17.
6
Using cocrystals as a tool to study non-crystallizing molecules: crystal structure, Hirshfeld surface analysis and computational study of the 1:1 cocrystal of (E)-N-(3,4-difluorophenyl)-1-(pyridin-4-yl)methanimine and acetic acid.利用共晶体作为研究非结晶分子的工具:(E)-N-(3,4-二氟苯基)-1-(吡啶-4-基)甲亚胺与乙酸1:1共晶体的晶体结构、 Hirshfeld表面分析及计算研究
Acta Crystallogr C Struct Chem. 2024 Aug 1;80(Pt 8):343-348. doi: 10.1107/S2053229624005187. Epub 2024 Jul 5.
7
Chalcogen-Bond-Assisted Formation of the N→C Dative Bonds in the Complexes between Chalcogenadiazoles/Chalcogenatriazoles and Fullerene C.硫属元素二唑/硫属元素三唑与富勒烯C形成的配合物中N→C配位键的硫属元素键辅助形成
Molecules. 2024 Jun 6;29(11):2685. doi: 10.3390/molecules29112685.
8
Supramolecular "baking powder": a hexameric halogen-bonded phosphonium salt cage encapsulates and functionalises small-molecule carbonyl compounds.超分子“泡打粉”:一种六聚体卤键合鏻盐笼包封小分子羰基化合物并使其功能化。
Chem Sci. 2023 Nov 28;15(1):298-306. doi: 10.1039/d2sc04615f. eCollection 2023 Dec 20.
9
A transferable quantum mechanical energy model for intermolecular interactions using a single empirical parameter.一种使用单一经验参数的分子间相互作用的可转移量子力学能量模型。
IUCrJ. 2023 Nov 1;10(Pt 6):754-765. doi: 10.1107/S2052252523008941.
10
Revisiting conventional noncovalent interactions towards a complete understanding: from tetrel to pnicogen, chalcogen, and halogen bond.重新审视传统非共价相互作用以实现全面理解:从碳族元素到氮族、氧族和卤键。
RSC Adv. 2023 Oct 27;13(45):31507-31517. doi: 10.1039/d3ra06078k. eCollection 2023 Oct 26.