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微波辅助燃烧合成ZnO:Eu纳米颗粒:燃料类型的影响

Microwave-Assisted Combustion Synthesis of ZnO:Eu Nanoparticles: Effect of Fuel Types.

作者信息

Rasouli Sousan, Arabi Amir-Masoud, Naeimi Alireza, Hashemi Seyed-Masoud

机构信息

Department of Nanomaterials & Nanocoatings, Institute for Color Science and Technology (ICST), Tehran, Iran.

Department of Inorganic Pigments and Glazes, Institute for Color Science and Technology (ICST), Tehran, Iran.

出版信息

J Fluoresc. 2018 Jan;28(1):167-172. doi: 10.1007/s10895-017-2179-y. Epub 2017 Oct 11.

Abstract

Nanoparticles of Europium oxide doped with Zinc oxide were synthesized via microwave-assisted combustion method. Citric acid as a simultaneous fuel and chelating agent and glycine as a fuel and mixture of these fuels were sleeted. X-Ray diffraction patterns (XRD) indicated the formation of ZnO structure with a few amount of EuO phase. Fourier transformation infra red (FTIR) spectra reveal the increase of ZnO bonds with glycine content of fuels mixture. Scanning electron microscope (SEM) images showed the conversion of nanosphere to spongy-like structure with respect to change of fuel mixtures from citric to glycine. From transmission electron microscopy (TEM) nanoparticles of a mean size 30 nm are observed Green fluorescence emission of different samples was due to activation of self activated center of ZnO structure through transition of electron from Eu to V sites.

摘要

采用微波辅助燃烧法合成了掺杂氧化锌的氧化铕纳米颗粒。选择柠檬酸作为同时作为燃料和螯合剂,甘氨酸作为燃料,并选用了这些燃料的混合物。X射线衍射图谱(XRD)表明形成了含有少量EuO相的ZnO结构。傅里叶变换红外(FTIR)光谱显示随着燃料混合物中甘氨酸含量的增加,ZnO键增加。扫描电子显微镜(SEM)图像显示,随着燃料混合物从柠檬酸变为甘氨酸,纳米球转变为海绵状结构。通过透射电子显微镜(TEM)观察到平均尺寸为30nm的纳米颗粒。不同样品的绿色荧光发射是由于电子从Eu跃迁到V位点激活了ZnO结构的自激活中心。

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