用于将5-羟甲基糠醛选择性氧化为2,5-二糠醛的多相介孔锰/钴氧化物催化剂。
Heterogeneous mesoporous manganese/cobalt oxide catalysts for selective oxidation of 5-hydroxymethylfurfural to 2,5-diformylfuran.
作者信息
Biswas Sourav, Dutta Biswanath, Mannodi-Kanakkithodi Arun, Clarke Ryan, Song Wenqiao, Ramprasad Ramamurthy, Suib Steven L
机构信息
Department of Chemistry, University of Wisconsin-Madison, 1101 University Avenue, Madison, Wisconsin 53706, USA.
出版信息
Chem Commun (Camb). 2017 Aug 22;53(86):11751-11754. doi: 10.1039/c7cc06097a.
We report a heterogeneous catalytic protocol for the oxidation of 5-hydroxymethylfurfural (HMF) to 2,5-diformylfuran (DFF) using a mesoporous manganese doped cobalt oxide material. The absence of precious metals and additives, use of air as the sole oxidant, and easy isolation of products, along with proper catalyst reusability, make our catalytic protocol attractive for the selective oxidation of HMF to DFF.
我们报道了一种使用介孔锰掺杂钴氧化物材料将5-羟甲基糠醛（HMF）氧化为2,5-二甲基呋喃（DFF）的多相催化方法。该方法不存在贵金属和添加剂，以空气作为唯一氧化剂，产物易于分离，且催化剂具有良好的可重复使用性，使得我们的催化方法对于将HMF选择性氧化为DFF具有吸引力。
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